Noncentrosymmetric K2Mn3(SO4)3F2·4H2O and Rb2Mn3(SO4)3F2·2H2O with pseudo-KTP structures

被引：5
|
作者：
Yang Zhou [1 ]
Yanqiang Li [2 ]
Qingran Ding [2 ]
Youchao Liu [2 ]
Yangxin Chen [2 ]
Xitao Liu [2 ,3 ]
Xiaoying Huang [2 ]
Lina Li [2 ,3 ]
Sangen Zhao [2 ,3 ]
Junhua Luo [2 ,3 ]
机构：
[1] College of Chemistry and Materials Science, Fujian Normal University
[2] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
[3] Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China
来源：
ChineseChemicalLetters | 2021年 / 32卷 / 01期
基金：
中国国家自然科学基金;
关键词：
D O I：
暂无
中图分类号：
TB34 [功能材料];
学科分类号：
080501 ;
摘要：
Two fluoride sulfates,K2Mn3(SO4)3F2·4 H2O(Ⅰ) and Rb2Mn3(SO4)3F2·2 H2O(Ⅱ) are obtained by water solution method.Single-crystal X-ray diffraction analysis indicated that they crystallize in space groups of Cmc21.Their structures feature a pseudo-KTP structure consisting of interconnecting[Mn3(SO4)3 F2(H2O)2]∞layers,which are further packing along the a axis with alkali metal cations balancing the charges.The structure relationships between the two compounds are discussed.Secondharmonic generation measurements manifest that Ⅰ and Ⅱ have similar second-harmonic generation responses of about 0.2 and 0.25 times that of KH2PO4.
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页码：263 / 265
页数：3
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