Ultrafast Optical Kerr Effect of ConjugatedSilver Phenylacetylide Complex Oligomer

被引:0
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作者
Yi Hui XU
Li LIN
Jia Gang LUO
Boon K. TEO
Zong Ju XIA
Ying Hua ZOU
Hut Ying CHEN
(1Department of Chemistry. University of Hinois at Chicago. Chicago. IL 60680. USA2Department of Physics. Mesoscopic Physics Laboratory. Peking University
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Silver phenylacetylide. conjugated complex. optical Kerr effect;
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O614.122 [银Ag];
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摘要
Silver phenylacetylide oligomer was found to exhibit prominent third-order nonlinearoptical property. With susceptibility x(3) of 2.4×10-14 esu (10-4 mol/L in 1:1 dimethylsulfoxide/CHCl3 mixed solution) and second-order hyperpolarizability γ of 5.18×10-72-32 esu viaheterodyned ultrafast optical Kerr effect measurement. It existed mainly as 1:1 complex oligomersand polymers as characterized by mass spectroscopy and elemental analysis etc.
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页码:793 / 794
页数:2
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