Aza-BODIPY molecular assembly at the liquid-solid interface driven by Br…F—BF interactions

被引：5

作者：

Yuchuan Xiao ^{[1
,2
,3
]}

Fangjian Cai ^{[4
]}

Xuan Peng ^{[1
,3
]}

Xiyuan Kang ^{[4
]}

Peng Lei ^{[1
,3
]}

Xin Li ^{[5
]}

Haijun Xu ^{[4
,6
]}

Xunwen Xiao ^{[2
]}

Bin Tu ^{[1
]}

Qingdao Zeng ^{[1
,3
]}

机构：

[1] CAS Key Laboratory of Standardization and Measurement for Nanotechnology,CAS Center for Excellence in Nanoscience,National Center for Nanoscience and Technology (NCNST)

[2] School of Materials and Chemical Engineering,Ningbo University of Technology

[3] Center of Materials Science and Optoelectronics Engineering,University of Chinese Academy of Sciences

[4] Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources,College of Chemical Engineering,Nanjing Forestry University

[5] CAS Center for Excellence in Nanoscience,Beijing Key Laboratory of Micro-Nano Energy and Sensor,Beijing Institute of Nanoenergy and Nanosystems,Chinese Academy of Sciences

[6] School of Chemistry and Chemical Engineering,Henan Normal University

来源：

Chinese Chemical Letters | 2021年 / 32卷 / 11期

基金：

中国国家自然科学基金; 美国国家科学基金会;

关键词：

D O I：

暂无

中图分类号：

O641.3 [分子间的相互作用、超分子化学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work,two aza-BODIPY derivatives,3,5-diphenyl-1,7-di(p-dodecyloxyphenyl)-aza-BODIPY(CJF)and 3,5-di(p-bromophenyl-1,7-di(p-dodecyloxyphenyl)-aza-BODIPY(2Br-CJF) acted as model molecules to form the self-assembly monolayers on the solid-liquid interface.With the utilizing of scanning tunnelling microscope(STM),we demonstrated that intermolecular Br…F—BF interactions existed in 2Br-CJF self-assembly structure and played an important role in strengthening the stability of 2Br-CJF self-assembly structure.This result is supported by density functional theory(DFT) calculation.

引用

页码：3566 / 3569

页数：4

共 35 条

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