Synthesis,Structure and Photoluminescent Property of a New 2D Zn(Ⅱ) Coordination Polymer Constructed by Biphenyl-3,3',5,5'-tetracarboxylate

被引：0

作者：

王记江 ^{[1
]}

曹培香 ^{[1
]}

高楼军 ^{[1
]}

付峰 ^{[1
]}

张美丽 ^{[1
]}

任宜霞 ^{[1
]}

侯向阳 ^{[1
]}

机构：

[1] Department of Chemistry and Chemical Engineering,Shaanxi Key Laboratory of Chemical Reaction Engineering,Yan’an University

来源：

Chinese Journal of Structural Chemistry | 2011年 / 12期

关键词：

biphenyl-3; 3; 5; 5’-tetracarboxylic acid; Zn(II); photoluminescent property;

D O I：

10.14102/j.cnki.0254-5861.2011.12.003

中图分类号：

O621.2 [有机化合物性质];

学科分类号：

070303 ; 081704 ;

摘要：

A new 2D Zn(II) coordination polymer,[Zn(btc)0.5(phen)]n(1,H4btc = biphenyl-3,3’,5,5’-tetracarboxylic acid,phen = 1,10-phenanthroline),has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis,elemental analysis and IR spectro-scopy.Complex 1 crystallizes in the triclinic system,space group P1 with a = 7.6878(6),b = 10.3453(8),c = 10.9589(9) ,α = 113.3540(10),β = 90.5460(10),γ = 90.4280(10)°,V = 800.09(11) 3,Z = 2,Dc = 1.696 Mg.m-3,μ = 1.566 mm-1,F(000) = 414,the final R = 0.0359 and wR = 0.0778 for 2441 observed reflections with I > 2σ(I).Complex 1 has a 2D layered network containing dinuclear Zn(II) structural units.The 2D layers are further linked by the phen molecules through π-π stacking interactions into a 3D supramolecular framework.The photoluminescent property of 1 was also studied in the solid state at room temperature.

引用

页码：1787 / 1790

页数：4

共 3 条

[1]

Synthesis, structure and properties of microporous metal–organic frameworks constructed from Ni(II)/Cd(II), Tpt and H 4 bpta[J] . Ze Chang,Da-Shuai Zhang,Tong-Liang Hu,Xian-He Bu.Inorganic Chemistry Communications . 2011 (7)

[2]

Effect of Different Carboxylates on a Series of Ag (I) Coordination Compounds with Benzoguanamine Ligand .2 Hao H J,Sun D,Li Y H,et al. Cryst. Growth Des . 2011

[3]

Syntheses,structures,and luminescent properties of two novel coordination polymers with dipicolinate and diimidazole ligands .2 Liu,T. F,Wu,W. F,Zhang,W. G,Cui,G. H. Anorg. Allg. Chem . 2011

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