Syntheses, Crystal Structures and Properties of Two New Zn Based Boron Imidazolate Frameworks

被引：0
作者：
毕明月 [1 ,2 ]
温一航 [1 ]
张海霞 [2 ]
张健 [2 ]
机构：
[1] Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces,Institute of Physical Chemistry,Zhejiang Normal University
[2] State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences
来源：
ChineseJournalofStructuralChemistry | 2021年 / 40卷 / 07期
关键词：
boron imidazolate frameworks; crystal structure; X-ray crystallography; luminescent;
D O I：
10.14102/j.cnki.0254-5861.2011-3068
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
Two new boron imidazolate frameworks (BIFs),Zn2[HBH(2-mim)3]2(1,2-PEA)2(EG)2(BIF-120,EG=ethylene glycol) and Zn[BH(2-mim)3](1,2-HPEA)(BIF-121),were successfully synthesized by mixing the KBH(2-mim)3ligand and the semirigid aromatic dicarboxylate ligand 1,2-benzenediacetic acid (1,2-H2PEA) under solvothermal conditions.In this paper,the two samples were structurally characterized by single-crystal X-ray diffraction and tested by infrared spectroscopy (IR),UV-visible spectroscopy (UV-Vis),thermogravimetric analysis TGA and X-ray powder diffractions.In addition,the solid-state luminescent properties of these crystals were also investigated.
引用
收藏
页码：865 / 870
页数：6
相关论文
共 24 条
  • [21] Syntheses, Structures, and Photoluminescence of a Series of d（10） Coordination Polymers with R-Isophthalate （R = -OH, -CH3, and -C（CH3）（3））[J] . Ma, LF,Wang, LY,Hu, JL,Wang, YY,Yang, GP.Crystal growth ＆ design . 2009 (12)
  • [22] Potent benzimidazole sulfonamide protein tyrosine phosphatase 1B inhibitors containing the Heterocyclic (S)-isothiazolidinone phosphotyrosine mimetic
    Combs, Andrew P.
    Zhu, Wenyu
    Crawley, Matthew L.
    Glass, Brian
    Polam, Padmaja
    Sparks, Richard B.
    Modi, Dilip
    Takvorian, Amy
    McLaughlin, Erin
    Yue, Eddy W.
    Wasserman, Zelda
    Bower, Michael
    Wei, Min
    Rupar, Mark
    Ala, Paul J.
    Reid, Brian M.
    Ellis, Dawn
    Gonneville, Lucie
    Emm, Thomas
    Taylor, Nancy
    Yeleswaram, Swamy
    Li, Yanlong
    Wynn, Richard
    Burn, Timothy C.
    Hollis, Gregory
    Liu, Phillip C. C.
    Metcalf, Brian
    [J]. JOURNAL OF MEDICINAL CHEMISTRY, 2006, 49 (13) : 3774 - 3789
  • [23] Syntheses, structures, and photoluminescence of three coordination polymers of cadmium dicarboxylates[J] . Zhang LY,Zhang JP,Lin YY,Chen XM.Crystal growth ＆ design . 2006 (7)
  • [24] A rationale for the large breathing of the porous aluminum terephthalate (MIL-53) upon hydration
    Loiseau, T
    Serre, C
    Huguenard, C
    Fink, G
    Taulelle, F
    Henry, M
    Bataille, T
    Férey, G
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (06) : 1373 - 1382
123