Syntheses, Crystal Structures and Properties of Two New Zn Based Boron Imidazolate Frameworks

被引：0
作者：
毕明月 [1 ,2 ]
温一航 [1 ]
张海霞 [2 ]
张健 [2 ]
机构：
[1] Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces,Institute of Physical Chemistry,Zhejiang Normal University
[2] State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences
来源：
ChineseJournalofStructuralChemistry | 2021年 / 40卷 / 07期
关键词：
boron imidazolate frameworks; crystal structure; X-ray crystallography; luminescent;
D O I：
10.14102/j.cnki.0254-5861.2011-3068
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
Two new boron imidazolate frameworks (BIFs),Zn2[HBH(2-mim)3]2(1,2-PEA)2(EG)2(BIF-120,EG=ethylene glycol) and Zn[BH(2-mim)3](1,2-HPEA)(BIF-121),were successfully synthesized by mixing the KBH(2-mim)3ligand and the semirigid aromatic dicarboxylate ligand 1,2-benzenediacetic acid (1,2-H2PEA) under solvothermal conditions.In this paper,the two samples were structurally characterized by single-crystal X-ray diffraction and tested by infrared spectroscopy (IR),UV-visible spectroscopy (UV-Vis),thermogravimetric analysis TGA and X-ray powder diffractions.In addition,the solid-state luminescent properties of these crystals were also investigated.
引用
收藏
页码：865 / 870
页数：6
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