A New 1D Zinc Coordination Polymer Constructed by 1-Naphthylacetate and 4,4'-bpy:Synthesis,Structure and Luminescent Property

被引：0

作者：

周建敏 ^{[1
]}

牛显春 ^{[2
]}

机构：

[1] College of Chemistry and Life Science,Guangdong University of Petrochemical Technology

[2] College of Chemical and Environmental Engineering,Guangdong University of Petrochemical Technology

来源：

Chinese Journal of Structural Chemistry | 2012年 / 03期

关键词：

zinc coordination polymer; crystal structure; luminescent;

D O I：

10.14102/j.cnki.0254-5861.2012.03.009

中图分类号：

O634 [元素有机聚合物];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

One new zinc coordination polymer,[Zn(NAA)2(4,4’-bpy)]n(1,HNAA = 1-naphthaleneacetic acid,4,4’-bpy = 4,4’-bipyridine),has been synthesized under hydrothermal conditions and characterized by elemental analysis,IR spectroscopy,thermogravimetric analysis(TGA),and single-crystal X-ray diffraction.Coordination polymer 1 is of monoclinic system,space group Cc with a = 9.8720(6),b = 16.7397(9),c = 17.0371(12) ,β = 104.8080(10)°,V = 2721.9(3)3,C34H26N2O4Zn,Z = 4,Mr = 591.94,Dc = 1.444 g/cm3,μ(MoKα) = 0.946 mm-1,F(000) = 1224,the final R = 0.0282 and wR = 0.0720 for 3300 observed reflections with I > 2σ(I).1 exhibits an interesting one-dimensional chain structure.Furthermore,the luminescent property of 1 has also been investigated.

引用

页码：361 / 366

页数：6

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