THE POLYELECTROLYTIC BEHAVIOURS OF ACIDIC AQUEOUS SOLUTIONS OF CHITOSAN IN THE PRESENCE OF EXTERNAL SALTS

被引:0
作者
余木火
周征龙
武秀阁
刘欣
机构
[1] Department
[2] Department of Chemical—fiber Technology
关键词
polyelectrolyte; chitin; viscosity; solution; empirical equation;
D O I
10.19884/j.1672-5220.1991.04.005
中图分类号
学科分类号
摘要
The viscosities of chitosan-HAC in aqueous solution with various amount of NaAC have beenmeasured.Based on the analysis of experimental data,an empirical equation is deduced to des-cribe the relationship between the intrinsic viscosity and the concentration of external salt in thechitosan solution:[η]=[η];+P/m;and another empirical equation is proposed for describing the variation of reduced viscosity ofchitosan solution as function of salt and chitosan concentrations:(η;/c);={D+A/(1+BC+HC;)}·{1-1/(([η];=0)/([η];-[η];)+P/m;)+(C;m;}where the first term represents the relationship between viscosity and polymer concentration in theabsence of external salt,while the second term represents the correction value on viscosity in thepresence of external salt.
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页码:34 / 39
页数:6
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Polyélectrolytes amphipathiques en milieu organique[J] . E. Pefferkorn,R. Varoqui.Colloid and Polymer Science Kolloid-Zeitschrift & Zeitschrift für Polymere . 1977 (6)