A Cadmium（II） Coordination Polymer: Crystal Structure and Fluorescent Property of [CdCl2（4,4'-bipyridine）] ∞

被引：0
作者：
LOU Ben-Yong WANG Rui-Hu XU Ying YUAN Da-Qiang ZHOU You-Fu HONG Mao-Chun② (State Key Laboratory of Structural Chemistry
机构：
来源：
结构化学 | 2004年 / 07期
基金：
中国国家自然科学基金;
关键词：
cadmium(Ⅱ); coordination polymer; crystal structure; fluorescence;
D O I：
10.14102/j.cnki.0254-5861.2004.07.007
中图分类号：
O631 [高分子物理和高分子物理化学];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The reaction of L-histidine, CdCl22.5H2O and 4,4-bipyridine in methane/water gave rise to a two-dimensional coordination polymer [CdCl2(4,4-bipyridine)] which has been characterized by single-crystal X-ray diffraction. The polymer crystallizes in the orthorhombic sys- tem, space group Cmmm with a = 12.083(7), b = 11.771(7), c = 3.781(2) ? V = 537.8(6) ?, Z = 2, C10H8N2CdCl2, Mr = 339.48, Dc = 2.097 g/cm3, F(000) = 328 and (MoK? = 2.490 mm-1. The final R = 0.0658 and wR = 0.1398 for 257 observed reflections with I≥2(I).
引用
收藏
页码：747 / 750
页数：4
相关论文
共 50 条
[41]   Zinc(II) coordination polymer with 4,4′-quinoline ligand [J].
Wang Wei .
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (07) :1306-1308
[42]   A two-dimensional copper(II) coordination polymer based on 2,4′-oxybis(benzoate) and 4,4′-bipyridine [J].
Tang, Long ;
Zhang, Juan ;
Liu, Xiao-Xia ;
Wang, Ji-Jiang ;
Fu, Feng .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2017, 73 :503-507
[43]   Synthesis, crystal structure and photoelectric property of two new coordination polymers constructed by longer-spanning suberic acid and 4,4′-bipyridine ligands [J].
Xie, Yan ;
Bai, Feng Ying ;
Li, Jing ;
Xing, Yong Heng ;
Wang, Zhuo ;
Zhao, Hai Yan ;
Pu, Zhi Feng ;
Ge, Mao Fa ;
Shi, Zhan .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2010, 77 (04) :749-754
[44]   Synthesis and crystal structure of a novel manganese coordination polymer constructed by 3,5-dimethylbenzoic acid with 4,4′-bipyridine [J].
Zhang Chun-Hua ;
Chen Man-Sheng ;
Kuang Dai-Zhi .
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (10) :1213-1216
[45]   Synthesis, Crystal Structure and Magnetic Property of the 2D Mn(II) Coordination Polymer Based on 4,4′-Bisimidazolylbiphenyl and m-Phthalic Acid [J].
Zhang Chun-Li ;
Qin Ling ;
Yang Qing-Xiang ;
Shi Zhi-Qiang ;
Zheng He-Gen .
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2013, 29 (10) :2157-2161
[46]   Synthesis and Crystal Structure of a Novel Manganese Coordination Polymer Constructed by 3,5-Dimethylbenzoic Acid with 4,4'-Bipyridine [J].
ZHANG Chun-Hua② CHEN Man-Sheng KUANG Dai-Zhi ② (Department of Chemistry and Materials Science .
Chinese Journal of Structural Chemistry, 2006, (10) :1213-1216
[47]   Synthesis, Crystal Structure and Fluorescence Property of Zinc(II) Coordination Polymer with 4,4′-Bis(benzimidazol-1-ylmethyl)biphenyl and Phthalate [J].
Tao Zhao-Lin ;
Cui Jie-Hu ;
Qin Ling ;
Zheng He-Gen .
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2012, 28 (12) :2633-2637
[48]   Hydrothermal synthesis and crystal structure of new coordination polymers with 2,2′-bipyridine-4,4′-dicarboxylic acid [J].
Yan, Shaohua ;
Zheng, Xiangjun .
JOURNAL OF MOLECULAR STRUCTURE, 2010, 964 (1-3) :52-57
[49]   The first coordination compound of 6-fluoro-nicotinate: the crystal structure of a one-dimensional nickel(II) coordination polymer containing the mixed ligands 6-fluoronicotinate and 4,4′-bipyridine [J].
Politeo, Nives ;
Pisacic, Mateja ;
Dakovic, Marijana ;
Sokol, Vesna ;
Kukovec, Boris-Marko .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 :500-+
[50]   Coordination polymers of lead(II) with 4,4′-bipyridine:: syntheses and structures [J].
Morsali, A ;
Mahjoub, A .
POLYHEDRON, 2004, 23 (15) :2427-2436
12345