[Co（H2O）(HPO4)]·H2O:TheLayeredDivalentMetalMonohydrogenphosphateStructure

被引：0

作者：

单永奎

戴立益

余淑媛

叶生荣

何鸣元

机构：

来源：

ChineseJournalofChemistry | 2002年 / 01期

关键词：

hydrothermal reaction; monohydrogenphosphate; hydrongen bonding; structure;

D O I：

暂无

中图分类号：

O641 [结构化学];

学科分类号：

070304 ; 081704 ;

摘要：

A new layered divalent metal monohydrogenphosphate [Co-(H 2O)(HPO 4)]·H 2O (1) was hydrothermally synthesized from the reaction of CoCl 2·6H 2O with H 3PO 4 in the presence of cis-Pt(NH 3) 2Cl 2 and ethylenediamine. The structure features extensive intra- and inter-layer hydrongen bonding among the hydrogenphosphate anoin, the coordinated water and the crystallization water. X-ray crystallographic parameters for 1 are orthorhombic Pnma (#62), a=1.7528(2), b=0.56158(7), c=0.47867(6) nm, V=0.47116(9) nm 3, Z=4

引用

页码：34 / 38+4 +4

页数：6