<正> The B-site ordered structure of Pb(Mg1/2W1/2)O3-Pb(Ti1-xZrx)O3 doped with ZnO ce-ramics is investigated by using a X-ray diffractometer,transmission electron microscopy andhigh resolution transmission electron microscopy.It is shown that(111)-type superlatticeexists in both of the XRD pattern and selected-area electron diffraction(SAED)images.Three kinds of(111)-type superlattice diffraction have been observed in[011]zone SAEDdark-field image by TEM.Two kinds of ordered structure,the large ordered regions(≥100nm)and the nanoscale ordered domains(=2-50nm),have been found by HREM.It issuggested that the dual peaks in the ε-T curve are caused by the complex dielectric proper-ties of the different ordered degree grains in the PMW-PZT doped with ZnO ceramics.