Optically active micelles from self-assembly of MPEG-b-PMALM copolymer in water

被引：0
|
作者：
Fa Bao Zhao Zhi Lei Liu Jian Ping Sun Liang Feng Ji Wen Hu~* Guangzhou Institute of Chemistry
机构：
来源：
ChineseChemicalLetters | 2009年 / 20卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Block copolymers; Chiroptical properties; Micelles; Circular dichroism(CD);
D O I：
暂无
中图分类号：
O631.3 [高聚物的化学性质];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Reported here is fabrication of optically active micelles with broad range of morphologies in water,such as spheres,cylinders, and vesicles,from self-assembly of poly（ethylene glycol）monomethyl ether-b-poly-（methacryloyl-L-leucine methyl ester） （MPEG-b-PMALM）copolymer,which was prepared via atom transfer radical polymerization（ATRP）from vinyl monomer bearing chiral amino acid moieties,N-methacryloyl L-leucine methyl ester（MALM）,using bromine（Br）end-capped poly（ethylene golycol）monomethylether（MPEG-Br）as macroinitiator in the presence of CuBr/Me;TREN as catalytic system.
引用
收藏
页码：231 / 234
页数：4
相关论文
共 50 条
  • [1] Optically active micelles from self-assembly of MPEG-b-PMALM copolymer in water
    Zhao, Fa Bao
    Liu, Zhi Lei
    Sun, Han Ping
    Feng, Liang
    Hu, Ji Wen
    CHINESE CHEMICAL LETTERS, 2009, 20 (02) : 231 - 234
  • [2] Synthesis of an optically active triblock copolymer and its self-assembly behavior in dioxane/water
    Zhang, J
    Yu, Y
    Wan, XH
    Chen, XF
    Zhou, QF
    ACTA POLYMERICA SINICA, 2005, (02): : 305 - 308
  • [3] Self-assembly triggered by self-assembly: Optically active, paramagnetic micelles encapsulated in protein cage nanoparticles
    Milian, Jealemy Galindo
    Brasch, Melanie
    Anaya-Plaza, Eduardo
    de la Escosura, Andres
    Velders, Aldrik H.
    Reinhoudt, David N.
    Torres, Tomas
    Koay, Melissa S. T.
    Cornelissen, Jeroen J. L. M.
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2014, 136 : 140 - 146
  • [4] Self-assembly of block copolymer micelles in an ionic liquid
    He, Yiyong
    Li, Zhibo
    Simone, Peter
    Lodge, Timothy P.
    Journal of the American Chemical Society, 2006, 128 (08): : 2745 - 2750
  • [5] Self-assembly of block copolymer micelles in an ionic liquid
    He, YY
    Li, ZB
    Simone, P
    Lodge, TP
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (08) : 2745 - 2750
  • [6] Self-Assembly of an Optically Active Conjugated Oligoelectrolyte
    Ortony, Julia H.
    Chatterjee, Tirtha
    Garner, Logan E.
    Chworos, Arkadiusz
    Mikhailovsky, Alexander
    Kramer, Edward J.
    Bazan, Guillermo C.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (21) : 8380 - 8387
  • [7] Effect of salt on self-assembly in charged block copolymer micelles
    Borisov, OV
    Zhulina, EB
    MACROMOLECULES, 2002, 35 (11) : 4472 - 4480
  • [8] Multiscale coarse graining of diblock copolymer self-assembly: From monomers to ordered micelles
    Pierleoni, C
    Addison, C
    Hansen, JP
    Krakoviack, V
    PHYSICAL REVIEW LETTERS, 2006, 96 (12)
  • [9] Enantioselective self-assembly of optically active magnets.
    Train, C
    Pointillart, F
    Troitskaya, LL
    Thouvenot, R
    Gruselle, M
    Verdaguer, MPJC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U1086 - U1086
  • [10] UCST-driven self-assembly and crosslinking of diblock copolymer micelles
    Roth, Peter J.
    Davis, Thomas P.
    Lowe, Andrew B.
    POLYMER CHEMISTRY, 2012, 3 (08) : 2228 - 2235
12345