The coupled negatively charged nitrogen-vacancy(NV;) center system is a promising candidate for scalable quantum information techniques.In this work,ionized nitrogen molecules are implanted into bulk diamond to generate coupled NV;center pairs.The two-photon autocorrelation measurement and optically detected magnetic resonance measurement are carried out to confirm the production of the NV;center pair.Also,both 1.3μs decoherence time and 4.9kHz magnetic coupling strength of the NV;center pair are measured by controlling and detecting the spin states.Along with nanoscale manipulation and detection methods,such coupled NV;centers through short distance dipole-dipole interaction would show high potential in scalable quantum information processes.