SynthesisandCrystalStructureof[Fe2V（μ3-O）（μ-O2CCH3）6（THF）3]Cl·3H2O

被引：0
作者：
ZHOU WenBo
CUI Yong
ZHANG LinNa
HE LingJie
CAI SuHua
CHEN BoFujian Institute of Research on the Structure of Matter the Chinese Academyof Sciences Fuzhou Fujian China [350002 ]
机构：
来源：
结构化学 | 1998年 / 05期
关键词：
synthesis; crystal structure; oxo-carboxylato compound;
D O I：
10.14102/j.cnki.0254-5861.1998.05.007
中图分类号：
O76 [晶体结构];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The compound [Fe2V(μ3-O) (μ-O2CCH3), (THF)3]Cl. 3H2O (THF=tetrahydrofuran) crystallizes in monoclinic system, space group C2, with cell di-mensions a= l2. 847(2), b= l5. 875 (6), c= lO. 211 (3) A, β= 109- 34 (3)', V=1965. 1(4) A3, Z= 2, D,c= 1. 73 g/cm'3 Mr= 838. 5 . F(000) = 1040, λ(MoKa) =14. 0 cm-1. The final R=0. 094, Rw= 0. O95 for 13O4 observed reflections with I≥3. 0σ (I). The result of structure analysis indicates that the framework of this com-pound is a typical trimeric oxo ccntered carboxylato compound.
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页码：341 / 344
页数：4
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