Synthesis and Characterization of a Novel Organic-Inorganic Hybrid Compound [Ni(DMF)6]3[PMo (12)O (40)]2

被引：0

作者：

龚云 ^{[1
]}

胡长文 ^{[1
]}

李晖 ^{[1
]}

李阳光 ^{[2
]}

王永慧 ^{[2
]}

机构：

[1] School of Science, Beijing Institute of Technology, Beijing 100081, China 2. Institute of Polyoxometalates Chemistry, Northeast Normal University, Changchun 130024, China

来源：

Journal of Beijing Institute of Technology(English Edition) | 2006年 / 03期

关键词：

polyoxometalates; Keggin; crystal structure; synthesis; nickel;

D O I：

10.15918/j.jbit1004-0579.2006.03.022

中图分类号：

O611.3 [性质];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound [Ni（DMF）6]3[PMo 12O 40]2 （DMF=N,N′-dimethyllformamide） was synthesized and structurally characterized by elemental analysis, IR, UV and single crystal X-ray diffraction. It crystallized in the trigonal system, space group R-3, a=1.591?7（2） nm, b=1.591?7（2） nm, c=3.226?9（7） nm, α=90.00°, β=90.00 °, γ=120.00°, V=7.080（2） nm3, Z=3 and R1=0.083?7. It consists of two Keggin polyoxometalates [PMo 12O 40] 3- linked together with three [Ni（DMF）6] 2+ cations through hydrogen bonding interaction.

引用

页码：348 / 351

页数：4