Synthesis and Crystal Structure of Lanthanum Nitrate with Methyl-2-pyridyl Ketone Benzoyl Hydrazone

被引：0

作者：

TAI Xishi YIN Xianhong LIU Debo and TAN Minyu College of Chemistry and Chemical Engineering Lanzhou University Lanzhou P R China Department of Chemistry Guangxi University for Nationalities Nanning P R China YU Kaibei Analysis and Measurement Center Chengdu Branch of Chinese Academy of Sciences Chengdu P R China ^{[1
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机构：

来源：

ChemicalResearchinChineseUniversities | 2003年 / 04期

关键词：

Synthesis; Lanthanum complex; Methyl-2-pyridyl ketone benzoyl hydrazone; Crystal structure;

D O I：

暂无

中图分类号：

O627 [元素有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

A novel La complex with methyl-2-pyridyl ketone benzoyl hydrazone has been synthesized and determined by single crystal X-ray diffraction. The crystal is monoclinic with space group C2/c, a =1 7081(3) nm, b =1 5660(3) nm, c =1 3512(3) nm, α=90 00°, β=94 39(1)°, γ=90 00°, V =3 6037(12) nm 3, Z =4 . The complex is a ten-coordinated one with a lanthanum ion surrounded by a N 4O 6 set. The crystal structure is stabilized by hydrogen bonds between water molecules and NO - 3 anions.

引用

页码：434 / 436

页数：3