Synthesis and Molecular Structure of 1,5-Diphenyl-3-phenacylthio-1H-1,2,4-triazole

被引：0

作者：

LIU TianBaoa b JIANG WenQinga ZOU JianPinga ZHANG Yonga aKey Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry and Chemical Engineering Suzhou University Jiangsu China bDepartment of Chemistry Chizhou Teachers College Chizhou China ^{[215006
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机构：

来源：

结构化学 | 2006年 / 08期

关键词：

triazole; 1-benzoyl-3-phenylaminothiourea; crystal structure;

D O I：

10.14102/j.cnki.0254-5861.2006.08.023

中图分类号：

O626.26 [三氮杂茂（三唑）];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound 1,5-diphenyl-3-phenacylthio-1H-1,2,4-triazole 2 (C22H17- N3OS, Mr = 371.45) was prepared by the reaction of 1-benzoyl-3-phenyl-aminothiourea 1 with 2-bromoacetophenone. The crystal is of triclinic, space group P1, a = 8.906(3), b = 9.853(3), c = 11.226(4) ?, α = 100.562(5), β = 101.285(5), γ =? 105.096(6)o, Z = 2, V = 903.7(5) ?3, Dc = 1.365 g/cm3, μ(MoKα) = 0.196 mm-1, F(000) = 388, the final R = 0.0506 and wR = 0.0985 for 2532 observed reflections (I > 2σ(I)). Its formation mechanism was proposed.

引用

页码：1019 / 1023

页数：5