Cyclopropanation of active methylene compounds with β-alkoxycarbonyl vinylsulfonium salts

被引：0

作者：

Shenquan Guo ^{[1
]}

Niuniu Zhang ^{[2
]}

Xiangzheng Tang ^{[2
]}

Zhifeng Mao ^{[2
]}

Xuejing Zhang ^{[2
]}

Ming Yan ^{[2
]}

Yining Xuan ^{[1
]}

机构：

[1] College of Pharmacy,Guangdong Pharmaceutical University

[2] Institute of Drug Synthesis and Pharmaceutical Process, School of Pharmaceutical Sciences, Sun Yat-sen University

来源：

ChineseChemicalLetters | 2019年 / 30卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Vinylsulfonium salt; Active methylene compound; Cyclopropanation;

D O I：

暂无

中图分类号：

O621.3 [有机合成化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient synthesis of β-alkoxycarbonyl vinylsulfonium salts had been developed. Their reaction with indene-1,3-diones and other active methylene compounds provided cyclopropane carboxylates in good yields. A tentative reaction mechanism was proposed.

引用

页码：406 / 408

页数：3