Identifying the Sources of Solutes in Karst Groundwater in Chongqing,China:a Combined Sulfate and Strontium Isotope Approach

被引：0
作者：
PU Junbing [1 ,2 ]
YUAN Daoxian [1 ,2 ]
ZHANG Cheng [1 ,2 ]
ZHAO Heping [1 ,2 ]
机构：
[1] Karst Dynamics Laboratory,Institute of Karst Geology,Chinese Academy of Geological Sciences
[2] International Research Center on Karst under the Auspices of UNESCO
来源：
ActaGeologicaSinica(EnglishEdition) | 2012年 / 86卷 / 04期
基金：
中国国家自然科学基金;
关键词：
sulfate isotope; strontium isotope; hydrogeochemistry; karst groundwater; Chongqing Municipality;
D O I：
暂无
中图分类号：
P641.3 [水文地球化学];
学科分类号：
0818 ; 081803 ;
摘要：
Groundwater from karst subterranean streams is among the world’s most important sources of drinking water supplies,and the hydrochemical characteristics of karst water are impacted by both natural environment and people.Therefore,the study of hydrochemistry and its solutes’ sources is very important to ensure the normal function of life support systems.In this paper,thirty-five representative karst groundwater samples were collected from different aquifers(limestone and dolomite) and various land use types in Chongqing to trace the sources of solutes and relative hydrochemical processes.Hydrogeochemical types of karst groundwater in Chongqing were mainly of the Ca-HCOtype or Ca(Mg)-HCOtype.However,some hydrochemical types of karst groundwater were the K+Na+Ca-SOtype(G25 site) or Ca-HCO+SOtype(G26 and G14 site),indicating that the hydrochemistry of these sites might be strongly influenced by anthropogenic activities or unique geological characteristics.The dissolved Sr concentrations of the studied groundwater ranged from 0.57 to 15.06μmmol/L,and theSr/Sr varied from 0.70751 to 0.71627.TheδS-SOfell into a range of-6.8‰-21.5‰,with a mean value of 5.6‰.The variations of bothSr/Sr and Sr values of the groundwater samples indicated that the Sr element was controlled by the weathering of limestone, dolomite and silicate rock.However,the figure ofSr/Sr vs.Sr/[K~++Na~+]showed that the anthropogenic inputs also obviously contributed to the Sr contents.For tracing the detailed anthropogenic effects,we traced the sources of solutes collected karst groundwater samples in Chongqing according to theδS value of potential sulfate sources.The variations of bothδS and 1/ SOvalues of the groundwater samples indicated that the atmospheric acid deposition(AAD), dissolution of gypsum(GD),oxidation of sulfide mineral(OS) or anthropogenic inputs(SF:sewage or fertilizer) have contributed to solutes in karst groundwater.The influence of oxidation of sulfide mineral,atmospheric acid deposit and anthropogenic inputs to groundwater in Chongqing karst areas was much widespread.
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页码：980 / 992
页数：13
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