由间苯二甲酸和Medpq配体构筑的一种新型零维铜(Ⅰ)的配合物的水热合成及晶体结构测定(英文)

被引：5

作者：

黄艳菊 ^{[1
]}

崔运成 ^{[2
]}

杜刚 ^{[3
]}

机构：

[1] 通化师范学院化学系

[2] 吉林师范大学化学学院

[3] 通化市第一中学

来源：

无机化学学报 | 2009年 / 25卷 / 10期

关键词：

配合物; 铜Ⅰ; 晶体结构;

D O I：

暂无

中图分类号：

O634 [元素有机聚合物];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A metal-organic Complex [Cu2(ipt)(Medpq)2]n(ipt=isophthalic acid,Medpq=2-methyldipyrido[3,2-f:2′,3′-h]quinoxaline) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,TG and single-crystal X-ray diffraction.Title compound crystallizes in the monoclinic system,space group C2/c,with a=2.389 2(6) nm,b=0.709 60(18) nm,c=1.922 2(5) nm,β=108.655(3),V=3.087 8(14) nm3,C38H24Cu2 N8O4,Mr=783.73,Dc=1.686 g.cm-3,Z=4,the final R=0.055 4 and wR=0.128 5.In the crystal structure,the copper atom is three-coordinated with one carboxylate oxygen atom from carboxylate groups and two nitrogen atoms from Medpq ligand,showing a slightly distorted triangle geometry.Furthermore,it exhibits a zero-dimensional structure with ipt-Cu-medpq as building units.CCDC: 747544.

引用

页码：1882 / 1884

页数：3

共 5 条

[1]

Hydrothermal Synthesis and Crystal Structure of a Cobalt（Ⅱ） Polymer with One-dimensional Chain Structure:[Co（phen）（BDC）（H2O）]n·0.5nH2BDC[J]. LIU Boa LI Xiu-Meib② CUI Yun-Chenga FENG Minga a (Department of Chemistry, Jilin Normal University, Siping, Jilin 136000, China) b (Department of Chemistry, Tonghua Teachers College, Tonghua, Jilin 134002, China).结构化学. 2007(02)

[2] 先进材料的设计——网络拓扑方法 [J].

朱莉娜 ;

廖代正 .

结构化学, 2003, (02) :125-132

[3]

Synthesis, structures, and magnetic properties of Fe2, Fe17, and Fe19 oxo-bridged iron clusters: The stabilization of high ground state spins by cluster aggregates. Powell, A. K,Heath, S. L,Gatteschi, D. et al. Journal of the American Chemical Society . 1995

[4]

SHELXL 97, Program for the Refinement of Crystal Structure. Sheldrick GM. University of Gǒttingen . 1997

[5]

Brian, M,Michael, J. Z. Chemical Reviews . 2001

← 1 →