Synthesis,Structure and Luminescent Property of a New Cd(Ⅱ) Complex Containing 2-Propyl-imidazole-4,5-dicarboxylate

被引：2

作者：

刘新芳 ^{[1
]}

王利亚 ^{[1
]}

马录芳 ^{[1
]}

李荣芳 ^{[1
]}

机构：

[1] College of Chemistry and Chemical Engineering,Luoyang Normal University

来源：

结构化学 | 2010年 / 29卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Cd(Ⅱ) complex; 2-propyl-imidazole-4; 5-dicarboxylate; crystal structure; luminescent property;

D O I：

10.14102/j.cnki.0254-5861.2010.02.021

中图分类号：

O626.23 [间二氮茂（咪唑）及其衍生物];

学科分类号：

070303 ; 081704 ;

摘要：

A new Cd(Ⅱ) complex([Cd(H2PIDC)2]n) with singly deprotonated 2-propyl-imidazole-4,5-dicarboxylate as bridging ligand was synthesized and characterized by X-ray diffraction method.Crystal data:monoclinic,space group P21/c,with a=8.2547(11),b=10.7071(15),c=13.9131(14),β=126.164(5)o,V=992.8(2)3,C16H18N4O8Cd,Mr=506.74,Z=2,Dc=1.695g/cm3,F(000)=508,μ=1.151 mm-1,R=0.0296 and wR=0.0812 for 1581 observed reflections.Singly deprotonated ligands(H2PIDC-) act as μ3-bridge and join the Cd(Ⅱ) atoms into a 2-D layer structure.The 2-D layers are further linked by intermolecular hydrogen bonds into a 3D network.The luminescent property of the complex was also investigated.

引用

页码：280 / 284

页数：5