Synthesis, Crystal Structure and Luminescent Properties of [Zn(bipy)2(H2O)4]·L·3H2O

被引：0
|
作者：
陈友存 [1 ]
沈菲 [1 ]
王彦 [1 ,2 ]
许军军 [1 ]
汪快兵 [1 ]
机构：
[1] Anhui Provincial Laboratory of Optoelectronic and Magnetism Functional Materials, School of Chemistry and Chemical Engineering, Anqing Normal University
[2] State Key Laboratory of Coordination Chemistry, Nanjing University
来源：
结构化学 | 2011年 / 30卷 / 09期
基金：
中国国家自然科学基金;
关键词：
zinc(Ⅱ) complex; crystal structure; π-π; interactions; hydrogen bonds;
D O I：
10.14102/j.cnki.0254-5861.2011.09.009
中图分类号：
O627.23 [锌族金属有机化合物];
学科分类号：
070303 ; 081704 ;
摘要：
A novel coordination complex [Zn(bipy)2(H2O)4]·L·3H2O (1, bipy = 4,4’-bipyridine, LHNa = aniline-2,5-disulfonic acid monosodium salt) has been synthesized from LHNa by using hydrothermal method and structurally characterized. The result indicates that complex 1 belongs to the monoclinic system, space group P21/c with a = 20.392(3), b = 7.4052(12), c = 23.843(3) , β = 116.253(10)°, V = 3.2291(8) 3, Z = 4, Dc = 1.553 g·cm-3, μ = 0.962 mm-1, F(000) = 1568, and the final R = 0.0497 and wR = 0.1290. The complex 1 has a 0-D discrete structure, and generates an infinite 3-D network with the aid of O–H…O hydrogen bonds and π-π interactions.
引用
收藏
页码：1251 / 1256
页数：6
相关论文
共 50 条
  • [1] Synthesis, Crystal Structure and Luminescent Properties of [Zn(bipy)2(H2O)4]•L•3H2O
    Chen You-Cun
    Shen Fei
    Wang Yan
    Xu Jun-Jun
    Wang Kuai-Bing
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 30 (09) : 1251 - 1256
  • [2] Synthesis and crystal structure of {Cu2(pdc)2(4,4′-bipy)(H2O)•3H2O}2
    Wen, YH
    Zhang, J
    Qin, YY
    Li, ZH
    Yao, K
    Chen, YB
    Cheng, HK
    Yao, YG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (09) : 1001 - 1004
  • [3] Synthesis and Crystal Structure of {Cu2（pdc）2（4,4'-bipy）(H2O)·3H2O}2
    WEN Yi-Hang ZHANG Jian QIN Ye-Yan LI Zhao-Ji KANG Yao CHEN Yu-Biao CHENG Jian-Kai YAO Yuan-Gen② (State Key Laboratory of Structural Chemistry
    结构化学, 2004, (09) : 1001 - 1004
  • [4] Synthesis and Crystal Structure of [Zn（FcCOO）2（2,2'-bipy）(H2O)]2·H2O
    胡久荣
    梁福沛
    Chinese Journal of Structural Chemistry, 2007, (07) : 793 - 796
  • [5] Synthesis and crystal structure of [Zn(FcCOO)2(2,2′-bipy)(H2O)]2•H2O
    Hu Jiu-Rong
    Liang Fu-Pei
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (07) : 793 - 796
  • [6] Synthesis and crystal structure of [{Zn(3-SBA)(2,2′-bipy)(H2O)2}•H2O]n
    Li, WG
    Wang, ZW
    Cai, Y
    Xu, ZJ
    Li, YZ
    Zheng, HG
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (12) : 1857 - 1860
  • [7] Synthesis and crystal structure of [Zn(H2O)4(C4H2O4)] • H2O
    XIe, HZ
    Zheng, YQ
    Shou, KQ
    JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (15) : 1291 - 1297
  • [8] Synthesis and crystal structure of [Ni(TSSB)(Bipy)(H2O)]•-4H2O
    Jiang, YM
    Zhang, SH
    Zhou, ZY
    Zhong, XX
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (01) : 89 - 92
  • [9] Crystal structure of [Co(bipy)(maleato) (H2O)3]·H2O (bipy = 2,2′-bipyridine)
    Cun-Gen Zhang
    Yong-Jun Leng
    Zi-Feng Ma
    De-Yue Yan
    Journal of Chemical Crystallography, 1999, 29 : 1081 - 1084
  • [10] Synthesis, Crystal Structure, Luminescent and Electrochemical Properties of the Complex [Cd(C9H8O3N)2(2,2′-bipy)(H2O)]2•(H2O)3
    Yang Ying-Qun
    Li Chang-Hong
    Li Wei
    Yi Zheng-Ji
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (09) : 1646 - 1650
12345