Synthesis,CrystalStructureandLuminescentPropertiesof[Zn（bipy）2（H2O）4]·L·3H2O

被引：0

作者：

陈友存 ^{[1
]}

沈菲 ^{[1
]}

王彦 ^{[1
,2
]}

许军军 ^{[1
]}

汪快兵 ^{[1
]}

机构：

[1] Anhui Provincial Laboratory of Optoelectronic and Magnetism Functional Materials, School of Chemistry and Chemical Engineering, Anqing Normal University

[2] State Key Laboratory of Coordination Chemistry, Nanjing University

来源：

结构化学 | 2011年 / 30卷 / 09期

关键词：

zinc(Ⅱ) complex; crystal structure; π-π; interactions; hydrogen bonds;

D O I：

10.14102/j.cnki.0254-5861.2011.09.009

中图分类号：

O627.23 [锌族金属有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

A novel coordination complex [Zn(bipy)2(H2O)4]·L·3H2O (1, bipy = 4,4'-bipyridine, LHNa = aniline-2,5-disulfonic acid monosodium salt) has been synthesized from LHNa by using hydrothermal method and structurally characterized. The result indicates that complex 1 belongs to the monoclinic system, space group P21/c with a = 20.392(3), b = 7.4052(12), c = 23.843(3) , β = 116.253(10)°, V = 3.2291(8) 3, Z = 4, Dc = 1.553 g·cm-3, μ = 0.962 mm-1, F(000) = 1568, and the final R = 0.0497 and wR = 0.1290. The complex 1 has a 0-D discrete structure, and generates an infinite 3-D network with the aid of O–H…O hydrogen bonds and π-π interactions.

引用

页码：1251 / 1256

页数：6