X-ray scintillation in lead-free double perovskite crystals

被引：0

作者：

Qingsong Hu ^{[1
]}

Zhenzhou Deng ^{[2
]}

Manchen Hu ^{[3
]}

Anjiang Zhao ^{[4
]}

Yaqi Zhang ^{[5
]}

Zhifang Tan ^{[1
]}

Guangda Niu ^{[1
]}

Haodi Wu ^{[1
]}

Jiang Tang ^{[1
]}

机构：

[1] Wuhan National Laboratory for Optoelectronics(WNLO), Huazhong University of Science and Technology (HUST)

[2] School of Information Engineering, Nanchang University

[3] School of Optical and Electronic Information, Huazhong University of Science and Technology (HUST)

[4] College of Life Science and Technology, Huazhong University of Science and Technology (HUST)

[5] College of Physics, Huazhong University of Science and Technology (HUST)

来源：

Science China(Chemistry) | 2018年 / 12期

基金：

中国国家自然科学基金;

关键词：

low toxic; scintillation; light yield; lanthanide; double perovskites;

D O I：

暂无

中图分类号：

O734 [晶体的光学性质];

学科分类号：

0803 ;

摘要：

Metal halide perovskites have shown great performance for various applications,including solar cells,light emitting diodes,and radiation detectors,but they still suffer from the toxicity of lead and instability.Here we report the use of lanthanide series as trivalent metals to obtain low toxicity and highly stable double perovskites（Cs;NaLnCl;,Ln=Tb or Eu）with high scintillation light yield.The crystals exhibit typical f-f transitions of lanthanide cations,while Cs;NaTbCl;exhibits strong green photoluminescence,and Cs;NaEuCl;exhibits red photoluminescence.Under X-ray radiations,the light yield of Cs;NaTbCl;reaches46600 photons MeV;,much higher than that of the commercially used（Lu,Y）;SiO;:Ce;crystals(LYSO,28500 photons MeV;),and previously reported lead-based perovskites(14000 photons MeV;).As a new member of lead-free perovskites,lanthanide-based double perovskites open up a new route toward radiation detections and potential medical imaging.

引用

页码：1581 / 1586

页数：6

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