Structural transitions in NaNH2 via recrystallization under high pressure

被引:0
作者
黄艳萍 [1 ]
黄晓丽 [1 ]
王鑫 [1 ]
张文亭 [1 ]
周迪 [1 ]
周强 [1 ]
刘冰冰 [1 ]
崔田 [1 ]
机构
[1] College of Physics, State Key Laboratory of Superhard Materials, Jilin University
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
high pressure; sodium amide; phase transition; recrystallization;
D O I
暂无
中图分类号
TB34 [功能材料];
学科分类号
080501 ;
摘要
Multiple phase transitions are detected in sodium amide(NaNH), an important hydrogen storage material, upon compression in diamond anvil cells(DAC) by using Raman spectroscopy and x-ray diffraction(XRD) measurements.Additional Bragg reflections appear on lower and higher angle sides of the original ones at ~1.07 GPa and 1.84 GPa,accompanied by obvious changes in Raman spectroscopy, respectively.It reveals that NaNHundergoes the high-pressure phase sequence(α–β–γ) up to 20 GPa at room temperature.Spectral analysis indicates an orthorhombic structure with PBAN space group for the γ phase.We also experimentally observe high pressure induced recrystallization in alkaline amide compounds for the first time.
引用
收藏
页码:325 / 329
页数:5
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