StudyonLuminescencePropertiesofaNovelRareEarthComplexEu（TTA）2（N-HPA）Phen

被引：0

作者：

张妍斐 ^{[1
]}

徐征 ^{[1
]}

吕玉光 ^{[2
]}

张福俊 ^{[1
]}

王勇 ^{[1
]}

张敬畅 ^{[2
]}

机构：

[1] Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University

[2] Institute of Modern Catalysis, Beijing University of Chemical Technology

来源：

Journal of Rare Earths | 2007年 / 02期

关键词：

energy transfer; ligand; electroluminescence; rare earth complex;

D O I：

暂无

中图分类号：

O482.31 [发光学]; O614.33 [镧系元素（稀土元素）];

学科分类号：

070205 ; 0805 ; 080502 ; 0809 ; 070301 ; 081704 ;

摘要：

A novel rare earth complex Eu(TTA)2(N-HPA)Phen (TTA=thenoyltrifluoroacetone, N-HPA=N-phenylanthranilic acid, and phen=1,10-phenathroline), which contains three different ligands, was synthesized. The Eu complex was blended with poly N-vinylcarbazole (PVK) in different weight ratios and spin coated into films. The luminescence properties of films were investigated and energy transfer between PVK and the complex was discussed. Multilayer structural devices consisting of ITO/PVK∶Eu(TTA)2(N-HPA)phen/BCP/Alq3/A1 were fabricated with PVK∶Eu(TTA)2(N-HPA) as light-emitting layer. Increasing the concentration of Eu in the PVK thin film would inhibit the emission of PVK to different degrees. Finally, the pure red luminescence of europium(Ⅲ) was observed when the doping weight ratio was approximately 1∶5, which indicated an effective energy transfer from PVK to rare earth complex.

引用

页码：143 / 147

页数：5