Syntheses, Crystal Structures, and Properties of Two Mixed-ligand Coordination Polymers: [Zn(bdc)(1,3-bimb)]n and {[Mn2(ox)2(1,3,5-tib)4/3]·4H2O}n

Two new coordination polymers,[Zn(bdc)(1,3-bimb)]n(1) and {[Mn2(ox)2(1,3,5tib)4/3]·4H2O}n(2)(H2ox = oxalic acid,H2bdc = terephthalic acid,1,3-bimb = 1,3-bis(imidazol-1ylmethyl)benzene,1,3,5-tib = 1,3,5-tri(imidazol-1-yl)benzene),were synthesized and characterized by elemental analysis,IR,powder X-ray diffraction(PXRD),and thermogravimetric(TG) analyses.X-ray diffracation analysis reveals that two kinds of zigzag chains [Zn(bdc)]n and [Zn(1,3-bimb)]n in compound 1 are interweaved to form a 3D 4-fold interpenetrated 66-dia framework.In compound 2,Mn(1) and Mn(2) are linked via 1,3,5-tib ligands to form two different nets of [Mn6(1,3,5-tib)6 ]n along the ab plane with inner-or outer-shape N-Mn-N angles,which are connected by 1D infinite [Mn2(ox)2 ]n chains via Mn-O bonds to result in a(3,3,3,4,4)-connected(4·8·10)3(4·82)3(4·83·102)6(82·104·3)3(83)4 topology.Moreover,the photoluminescence of 1 has been investigated.The crystal of 1 crystallizes in orthorhombic,space group Pna2 with a = 13.2267(6),b = 9.1717(4),c = 17.4492(8),V = 2116.79(16)3,Z = 4,C22 H18N4O4 Zn,Mr = 467.77,Dc = 1.468 g/cm3,F(000) = 960 and μ(MoKα) = 1.197 mm-1.The final R = 0.0280 and wR = 0.0618 for 3695 observed reflections with I > 2(I) and R = 0.0389 and wR = 0.0653 for all data.The crystal of 2 crystallizes in rhombohedral,space group R-3 with a = 22.080(8),c = 31.19(2),V = 13167(11) 3,Z = 18,C24 H25 Mn2 N8 O13,Mr = 743.40,Dc = 1.688 g/cm3,F(000) = 6822 and μ(MoKα) = 0.945 mm-1.The final R = 0.0429 and wR = 0.1035 for 5160 observed reflections with I > 2(I) and R = 0.0824 and wR = 0.1244 for all data.