Synthesis,Crystal Structure and Fluorescent and Thermal Stability Properties of the Zinc(Ⅱ) Complex [Zn(C15H11O3)2(C12H8N2)2]·5H2O

被引：0

作者：

李昶红 ^{[1
]}

李薇 ^{[2
,3
]}

胡汉祥 ^{[1
]}

蒋美丽 ^{[1
]}

机构：

[1] Department of Chemical Engineering, Hunan Institute of Technology

[2] Department of Chemistry and Materials Science, Hengyang Normal University

[3] School of Materials Science and Engineering, Central South University

来源：

Chinese Journal of Structural Chemistry | 2014年 / 06期

关键词：

zinc(II) complex; synthesis; fluorescent and thermal stability properties;

D O I：

10.14102/j.cnki.0254-5861.2014.06.022

中图分类号：

O627.23 [锌族金属有机化合物]; O741 [晶体结构数据（结构报告）];

学科分类号：

0702 ; 070205 ; 0703 ; 070303 ; 080501 ; 081704 ;

摘要：

A new complex has been synthesized with o-methylbenzoyl-benzoic acid(HL) and 1,10-phenanthroline(phen) in the mixture of water and ethanol. It crystallizes in monoclinic, space group C2/c with a = 13.6328(18), b = 17.7876(18), c = 19.998(2), β = 104.720(4)o, C54H48N4O11Zn, Mr = 994.33, V = 4690.2(9)3, Dc = 1.408 g/cm3, Z = 4, F(000) = 2072, μ(MoKα) = 0.59 mm-1, R = 0.0736 and wR = 0.2029. The crystal structure shows that the zinc ions are coordinated with two oxygen atoms from two HL molecules and four nitrogen atoms from two phen molecules, forming distorted octahedral coordination geometry. The fluorescent and thermal stability properties of the complex are studied. The result shows that it has one fluorescent emission band at around 412 nm. In addition, the complex is stable under 210 ℃.

引用

页码：947 / 951

页数：5

共 5 条

[1] Synthesis,Crystal Structure,Thermal Stability and Luminescent Properties of a New 2D Zinc Complex [J].