Synthesis, Crystal Structure and Characterization of a New Mononuclear Zn(Ⅱ) Complex from Schiff-base Ligand

被引：0
|
作者：
陈军 [1 ]
许兴友 [1 ]
高健 [2 ]
李艳辉 [1 ]
徐国想 [1 ]
机构：
[1] Department of Chemical Engineering, Huaihai Institute of Technology
[2] Materials Chemistry Laboratory, Nanjing University of Science & Technology
来源：
Chinese Journal of Structural Chemistry | 2007年 / 06期
关键词：
zinc; Schiff-base; mononuclear; crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2007.06.002
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
A new mononuclear [Zn(H-1L)2] (L = 1H-indole-3-ethylene-salicylaldimine) was synthesized through the reaction of Zn(Ac)2, salicylaldehyde and tryptamine in hot ethanol solution and characterized by X-ray crystal structure analysis. The crystal belongs to monoclinic, space group P21/n with a = 15.014(2), b = 10.857(1), c = 17.489(1) , β = 95.49(1)°, V = 2837.8(5) 3, Z = 4, Dc = 1.386 g/cm3, μ = 0.904 mm-1, F(000) = 1232, the final R = 0.0463 and wR = 0.0890 for 4990 independent reflections. In the complex, the Zn2+ ion presents a distorted N2O2 tetrahedral coordination involving two H-1L ligands.
引用
收藏
页码：632 / 636
页数：5
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