[H2N（C2H4）2NH2]4（H3O）[PMo2VMo6VIV4IVO40(VIVO)2]·H2O:ANewHighlyReduced,BicappedPseudo-KegginVanadylpolymolybdophosphate

被引：0

作者：

李阳光

王恩波

德格吉乎

张宏

胡长文

胡宁海

贾恒庆

机构：

来源：

ChineseJournalofChemistry | 2002年 / 10期

关键词：

vanadylpolymolybdophosphate; highly reduced; hydrothermal synthesis; crystal structure; pseudo-Keggin;

D O I：

暂无

中图分类号：

O641 [结构化学];

学科分类号：

070304 ; 081704 ;

摘要：

A new vanadylpolymolybdophosphate, [H 2N(C 2H 4) 2NH 2] 4-(H 3O)[PMo V 2Mo VI 6V IV 4O 40(V IVO) 2]·H 2O, was hydrothermally synthesized and structurally characterized by elemental analyses, IR, UV-vis, XPS, ESR spectra, and single crystal X-ray diffraction analysis. The compound contains an unusual highly reduced pseudo-Keggin type polyoxoanion with nine negative charges and exhibits an interesting phosphorus-centered alternate layer arrangement of molybdenum and vanadium oxides.

引用

页码：933 / 936

页数：4