Synthesis and Structural Characterization of a Cyano-bridged 1-D Lanthanum(Ⅲ)-iron(Ⅲ) Complex [La(DMSO)5(H2O)](μ-CN)2[Fe(CN)4]·H2O

被引：0

作者：

陈文通 ^{[1
]}

郭国聪 ^{[2
]}

蔡丽珍 ^{[2
]}

陈惠芬 ^{[2
]}

徐刚 ^{[2
]}

黄锦顺 ^{[2
]}

机构：

[1] College of Chemistry and Chemical Engineering,Jiangxi Province Key Laboratory of Coordination Chemistry,Jinggangshan University

[2] State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences

来源：

Chinese Journal of Structural Chemistry | 2007年 / 10期

关键词：

crystal structure; cyano-bridged; lanthanum complex; Prussian blue;

D O I：

10.14102/j.cnki.0254-5861.2007.10.018

中图分类号：

O621.1 [有机化学理论、物理有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new lanthanumⅢ-ironⅢ complex [La(DMSO)5(H2O)](μ-CN)2[Fe(CN)4]·H2O 1 (DMSO=dimethylsulfoxide) has been prepared by a facile approach,ball-milling method,and characterized by X-ray diffraction. The crystal belongs to monoclinic,space group P21/n with a= 9.7125(3),b=21.5336(7),c=14.3804(5),β=93.242(3)o,C16H34FeLaN6O7S5,Mr=777.55,V =3002.8(2)3,Z=4,Dc=1.720 g/cm3,S=1.053,μ(MoKα)=2.278 mm–1,F(000)=1564,R= 0.0490 and wR=0.1270. The crystal structure analysis of 1 reveals a slightly distorted square-antiprism eightfold-coordinated La(Ⅲ) ion and a 1-D zigzag chain structure extending through the Fe-CN-La-NC-Fe linkages. The [La(DMSO)5(H2O)](μ-CN)2[Fe(CN)4] species are held together via hydrogen bonds to form a three-dimensional framework.

引用

页码：1239 / 1242

页数：4

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