Novel clicked tetrathiafulvalene-calix[4]arene assemblies:Synthesis and intermolecular electron transfer toward p-chloranil

被引：3

作者：

Bang-Tun Zhao ^{[1
]}

Xiao-Min Zhu ^{[2
]}

Xiu-Hua Chen ^{[2
]}

Zhen-Ning Yan ^{[2
]}

Wei-Min Zhu ^{[2
]}

机构：

[1] College of Chemistry and Chemical Engineering,Luoyang Normal University

[2] College of Chemistry and Molecular Engineering,Zhengzhou University

来源：

Chinese Chemical Letters | 2013年 / 24卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Tetrathiafulvalene; Calix[4]arene; Click reaction; Chloranil; Intermolecular electron transfer;

D O I：

暂无

中图分类号：

O621.3 [有机合成化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two tetrathiafulvalene-calix[4]arene assemblies（TTF-calix-1 and TTF-calix-2） have been synthesized by the click reaction.Both their cyclic voltammograms show,as expected,two one-electron quasi-reversible redox behavior.The UV-vis absorption spectra studies show that these two assemblies undergo progressive oxidation at the TTF moiety in presence of increasing amounts of Cu;or Hg;. Moreover,the absorption studies show intermolecular electron transfer between compounds TTF-calix- 1 or TTF-calix-2 and p-chloranil may be promoted by specific metal ions such as Pb;,Sc;etc.

引用

页码：573 / 577

页数：5

共 12 条

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