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Direct suprafacial 1,3-hydrogen migration of 1,1-dimethyl-2-(9-phenanthryl)cyclopropane
被引：0
作者：
WU Guo-Sheng MA Yun-Fei LI Zhen-Lian Shanghai Institute of Organic Chemistry
Academia Sinica
ShanghaiXU Jian-Hua Department of Chemistry
Nanjing University
Nanjing
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关键词：
Direct suprafacial 1,3-hydrogen migration of 1,1-dimethyl-2;
phenanthryl)cyclopropane;
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摘要：
<正> Irradiation of the title compound with two D-labeled methyl groups gave 2-methyl-d3-4-（9-phenanthryl）-1-butene-d3,which was eluciated on the bases of the spectral evidences andchemical degradation.Based on the discussions of MO following and bond order change betweenthe designed basis orbital pairs on excitation,the most reasonable ring-opening mode of the titlecompound appeared to be the direct suprafacial 1,3-hydrogen migration.
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页码：338 / 344
页数：7
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