Enthalpy of Mixing of Liquid Al-Cr and Cr-Ni Alloys

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作者
PSaltykov VTWitusiewicz IArpshofen HJSeifert and FAldingerMaxPlanckInstitut fur Metallforschung and Universitat Stuttgart Institut fiir Nichtmetallische Anorganische Materialien Pulvermetallurgisches Laboratorium Heisenbergstr D S [5 ,70569 ]
机构
关键词
Al-Cr; Cr-Ni; Liquid alloys; Enthalpy of mixing; Isoperibolic calorimetry;
D O I
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中图分类号
TG146.2 [轻有色金属及其合金];
学科分类号
080502 ;
摘要
The partial and the integral enthalpies of mixing of liquid Al-Cr and Ni-Cr binary alloys have been determined by high temperature isoperibolic calorimetry at 1723±5 K and 1729±5 K, respectively. The results were analytically described by the thermodynamically adapted power series (TAPS). The enthalpies of mixing values for both binary liquid melts are small and negative and in good agreement with the available literature data. Minima of the mixing enthalpies of liquid Al-Cr and Ni-Cr alloys are -7.0 kJ·mol-1 at 46 at. pct Cr and -3.0 kJ·mol-1 at 37 at. pct Cr, respectively.
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页码:167 / 170
页数:4
相关论文
共 2 条
[1]  
The margules concept: The basis of modern Algebraic representations of thermodynamic excess properties[J] . J. Tomiska,A. Neckel.Journal of Phase Equilibria . 1996 (1)
[2]  
Activities in dilute solutions of chromium and iron in nickel at 1600° by mass spectrometry[J] . Sigurd Wagner,D. J. Shade,G. R. St. Pierre.Metallurgical Transactions . 1972 (1)