Synthesis and Crystal Structure of a Magnesium Metal-organic Framework

被引：1
|
作者：
吴兆锋 [1 ,2 ]
冯美玲 [1 ]
胡冰 [1 ]
黄小荥 [1 ]
赵玉宝 [2 ]
机构：
[1] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
[2] School of Chemistry and Chemical Engineering, University of South China
来源：
结构化学 | 2011年 / 30卷 / 11期
关键词：
solvothermal synthesis; magnesium; metal organic framework; crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2011.11.010
中图分类号：
O621.1 [有机化学理论、物理有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A magnesium metal organic framework, [NH2(CH3)2][N(CH3)4][Mg5(bpdc)3(O2CH)6]· 3H2O (1, bpdcH2 = 4,4′-biphenyldicarboxylic acid), has been solvothermally synthesized and structurally characterized. 1 crystallizes in the trigonal system, space group R-3, with a = 11.3427(3), c = 41.5662(18) , V = 4631.3(3) 3, Z = 3 and the final R = 0.0457. Its structure features a pillared-layered three-dimensional network with 8.21  cavities, in which cationic [NH2(CH3)2]+ or [N(CH3)4]+ and lattice water molecules are located. Thermal stability of the title compound has also been investigated.
引用
收藏
页码：1585 / 1590
页数：6
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