Electrocatalytic Oxidation of Vitamin B6 by 4-Hydroxy- 2,2,6,6-tetramethylpiperidine-N-oxyl

被引：2
|
作者：
李燕
文小林
刘中立
机构：
[1] National Laboratory of Applied Organic Chemistry, Lanzhou University,National Laboratory of Applied Organic Chemistry, Lanzhou University,National Laboratory of Applied Organic Chemistry, Lanzhou University Lanzhou, Gansu 730000, China
[2] Department of Management, Zhejiang Pharmaceutical College, Ningbo, Zhejiang 315100, China, Lanzhou, Gansu 730000, China , Lanzhou, Gansu 730000, China
来源：
ChineseJournalofChemistry | 2004年 / 11期
基金：
中国国家自然科学基金;
关键词：
cyclic voltammetry; catalytic electrooxidation; vitamin B6; nitroxide;
D O I：
暂无
中图分类号：
O621 [有机化学一般性问题];
学科分类号：
070303 ; 081704 ;
摘要：
The electrochemistry of pyridoxine (vitamin B6, VB6) was studied by cyclic voltammetry at a glassy carbon electrode. The electrochemical response of VB6 could be significantly enhanced by using 4-hydroxy-2,2,6,6-tetra- methylpiperidine-N-oxyl (HO-TEMPO) as a mediator via an electrocatalytic EC’ mechanism with the oxoammo-nium ion of HO-TEMPO as the active oxidant. The catalytic rate constant was determined to be 5.4×103 (mol L-1)-1s-1 by using chronoamperometry.
引用
收藏
页码：1356 / 1358
页数：3
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