Polymerization of isoprene catalyzed by neodymium heterocyclic Schiff base complex

被引：0
|
作者：
Lei Zhang Xu Feng Ni Wei Lin Sun~* Zhi Quan Shen Institute of Polymer Science
机构：
来源：
ChineseChemicalLetters | 2008年 / 06期
关键词：
Heterocyclic Schiff base; Neodymium complex; Isoprene; Coordination polymerization;
D O I：
暂无
中图分类号：
O631.5 [聚合反应、缩聚反应];
学科分类号：
摘要：
Neodymium-based heterocyclic Schiff base complex was prepared and applied for the coordination polymerization of isoprene. This complex polymerized isoprene to afford products featuring high cis-1,4 stereospecificity（ca.95%）and high molecular weight （ca.10;）in the presence of the triisobutyl aluminium（AliBu;）as cocatalyst.The microstructure of obtained polyisoprene was investigated by FTIR,;H NMR.Two different kinds of active centers in the catalyst system were examined by GPC method.
引用
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页码：734 / 738
页数：5
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