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Synthesis and Crystal Structure of N-cyclopropyl-9 -(3,4-dicholophenyl)-1,2,3,4,5,6,7,8,9,10-decahydroacridine -1,8-dione under Microwave Irradiation
被引：0
作者：
FENG You-Jian JIA Run-Hong TU Shu-Jiang② ZHANG Xiao-Jin JIANG Bo ZHANG Yan ZHANG Jun-Yong (Department of Chemistry
机构：
基金：
中国国家自然科学基金;
关键词：
acridine;
synthesis;
microwave irradiation;
crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2005.12.018
中图分类号：
O621.3 [有机合成化学];
学科分类号：
070303 ;
081704 ;
摘要：
The N-cyclopropyl-9-(3,4-dicholophenyl)-1,2,3,4,5,6,7,8,9,10-decahydroacri- dine-1,8-dione was synthesized by the reaction of 1,3-cyclohexanedione, N-cyclopropylamine and 3,4-dicholoaldehyde in water and glycol under microwave irradiation. Its crystal structure was determined by single-crystal X-ray diffraction analysis. It possesses P212121 space group, with a = 9.9103(5), b = 13.3597(8), c = 14.5633(8) ?, V = 1928.16(18) ?3, Mr = 402.30, Z = 4, Dc = 1.386 g/cm3, λ = 0.7107 ?, μ(MoKα) = 0.354 mm?1 and F (000) = 840. The structure was refined to R = 0.0280 and wR = 0.0757. In the structure, the pyridine ring adopts a boat conformation.
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页码：1457 / 1461
+1353
页数：6
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