ChargedisproportionationinducedexchangebiasinLa0.5Ca0.5FeO3-δ

被引:0
作者
LIANG YaQiong [1 ,2 ]
ZHANG XiangQun [2 ]
JIN JinLing [2 ]
ZHAN QingFeng [3 ]
CHENG ZhaoHua [2 ]
机构
[1] Logistic School,Beijing Wuzi University
[2] State Key Laboratory of Magnetism,Institute of Physics,Chinese Academy of Sciences
[3] Key Laboratory of Magnetic Materials and Devices,Ningbo Institute of Material Technology and Engineering,Chinese Academy of Sciences
关键词
exchange bias; charge disproportionation; cluster glass;
D O I
暂无
中图分类号
O611.4 [无机合成化学];
学科分类号
070301 ; 081704 ;
摘要
We observed an exchange bias effect in La0.5Ca0.5FeO3 perovskite compound.The exchange bias is associated with the charge disproportionation transition from Fe4+ions to Fe3+and Fe5+ions below 175 K.The competition between the ferromagnetic interaction of Fe3+and Fe5+ions and the antiferromagnetic one of Fe3+and Fe3+ions results in a unidirectional anisotropy in the cluster-glass system.An antiferromagnetically interfacial exchange coupling constant Ji1.95 meV at the cluster-glass region was yielded by fitting the cooling field-dependence of the exchange bias field.
引用
收藏
页码:2085 / 2089
页数:5
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