Kinetic and products study of the gas-phase reaction of Lewisite with ozone under atmospheric conditions

被引：1
|
作者：
Haitao Wang [1 ]
Yuanpeng Zhang [1 ]
Xiaodi Guo [1 ]
Yusheng Shao [1 ]
Runli Gao [1 ]
Dejian Liang [1 ]
Hao Sun [2 ]
机构：
[1] State Key Laboratory of Nuclear Biological and Chemical Protection for Civilians
[2] Institute of Functional Material Chemistry,Faculty of Chemistry,Northeast Normal University
来源：
Journal of Environmental Sciences | 2016年 / 40卷 / 02期
关键词：
Rate constant; Lewisite; Ozone; Haloalkenes;
D O I：
暂无
中图分类号：
X51 [大气污染及其防治];
学科分类号：
0706 ; 070602 ;
摘要：
The rate constant for the gas-phase reaction of O;and Lewisite was studied in air using the smog chamber technique. The experiments were carried out under pseudo-first-order reaction conditions with [O;] [Lewisite]. The observed rate constant of O;with Lewisite was（7.83 ± 0.38） × 10;cm;/（molecule·sec） at 298 ± 2 K. Lewisite was discussed in terms of reactivity with O;and its relationship with the ionization potential. Our results show that the rate constant for the gas-phase reaction of O;with Lewisite is in line with the trend of the rate constants of O;with haloalkenes.
引用
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页码：3 / 9
页数：7
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