Two Novel Coordination Polymers with(6,3) Topology Constructed by an Imidazole-containing Isophthalic Ligand:Syntheses,Structures and Luminescence Properties

被引：3
作者：
李斌 [1 ]
方王建 [1 ]
刘淑芹 [1 ]
赵河 [1 ]
张建军 [1 ]
机构：
[1] Chemistry Department,Dalian University of Technology
来源：
Chinese Journal of Structural Chemistry | 2020年 / 39卷 / 01期
基金：
中国国家自然科学基金;
关键词：
coordination polymer; crystal structure; π-π stacking interaction; luminescence;
D O I：
10.14102/j.cnki.0254-5861.2011-2388
中图分类号：
O634 [元素有机聚合物];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two novel coordination polymers, [Zn(;NIPA)（DMSO）];（1） and [Cd(;NIPA)-（DMSO）];（2）(H;NIPA = 5-(6-（1 H-imidazol-1-yl）-1,3-dioxo-1 H-benzo[de]iso-quinolin-2（3H）-yl)isophthalic acid, DMSO = dimethylsulfoxide), were prepared under solvothermal conditions through the reactions of Zn;/Cd;and a new imidazole-containing isophthalic ligand H;ImNIPA. The compounds were fully characterized by elemental analysis, FT-IR spectroscopy, powder X-ray diffraction analysis and X-ray single-crystal diffraction analysis. Both 1 and 2 are two-dimensional（2D） coordination layers via the combination of 3-connected metal nodes and;NIPA;linker, featuring（6, 3） honeycomb-type topology. In addition, the 2D layers in the two compounds are further extended into 3D supramolecular frameworks via π-π stacking interactions. Finally, the thermal-stability and solid-state luminescence properties of them were also investigated.
引用
收藏
页码：110 / 117
页数：8
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