Synthesis and self-assembly behavior of 2,5-diphenylethynyl thiophene based bolaamphiphiles

被引：3
|
作者：
Shou-Bing Yi [1 ]
Hong-Fei Gao [1 ]
Quan Li [1 ]
Ya-Fei Ye [1 ]
Na Wu [1 ]
Xiao-Hong Cheng [1 ]
机构：
[1] Key Laboratory of Medicinal Chemistry for Natural Resources, Chemistry Department, Yunnan University
来源：
ChineseChemicalLetters | 2015年 / 26卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Lyotropic liquid crystals Bolaamphiphiles Bent core Acetylene;
D O I：
暂无
中图分类号：
O626.12 [硫杂茂（噻吩）族];
学科分类号：
070303 ; 081704 ;
摘要：
Novel T-shaped bolaamphiphiles consisting of a bent 2,5-diphenylethynyl thiophene rigid core with two terminal glycerol units and a lateral n-alkyl chain have been synthesized via Kumuda and Sonogashira coupling reactions as key steps. Their liquid crystalline behavior was investigated by polarizing optical microscopy(POM), differential scanning calorimetry(DSC), and X-ray diffraction(XRD). All such bolaamphiphiles can self-organize into square honeycomb LC phases with p4 mm symmetries in the presence of water. UV and PL measurements indicate fluorescent properties making them potential candidates for application in fluorescence sensor devices.
引用
收藏
页码：872 / 876
页数：5
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