Studies on Functionally Substituted n5-Cyclopentadienyl Transition-Metal Compounds --Synthesis and Crystal Structure of η5-CH3COC5H4W(CO)3CH2C5H5

被引：0

作者：

Song Licheng

Yang Hua and Hu Qingmei (Department of Chemistry

Nankai University

Tianjin)Zhou Zhongyuan (Chengdu Center of Analysis and. Determination

Academia Sinica

Chengdo)

机构：

来源：

Chemical Journal of Chinese Universities | 1990年 / 01期

关键词：

η5-Acetylcyclopentadienyl; 6-Benzyl tungsten compounds; Synthesis; Crystal structure;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

<正> Reaction of benzyl chloride with η5-CH3COC5H4W(CO)2Na formed in situ from η6-CH3CO C6H4Na and W(CO)2 gives η6-CH3COC6H4W(CO)3CH2C5H5.The single crystal structure of the product was determined by X-ray diffraction method. It crystallizes in the triclinlc space group P1 with unit cell parameters a= 10.199(5),b=12.116(7), c=14.207(6)A;a=69.47(5),β=72. 38(3),γ= 85.89(4);V= 1569. 9A3, Dc= 1.98 g/cm2; Z=4. Least-square refinement led to final R value of 0. 0539 and Rw value of 0. 0553, based on 3548 independent observed reflections.

引用

页码：14 / 19

页数：6