Highly Chemical and Regio-selective Catalytic Oxidation with a Novel Manganese Catalyst

被引：0

作者：

刘斌

陈怡

余成志

沈征武

机构：

[1] ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai,China,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai,China,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai,China,ShanghaiInstituteofOrganicCh

来源：

Chinese Journal of Chemistry | 2003年 / 07期

关键词：

TACN; catalytic oxidation; maganese; benzaldehyde;

D O I：

暂无

中图分类号：

O643.3 [催化];

学科分类号：

081705 ;

摘要：

<正> The chemical selectivity of a novel active manganese compound[Mn2IVμ-O)3（TMTACN）2]（PF6）2 （1）in catalytic oxidation re-actions depended on the structure of substrates and 1 was ableto catalyze the oxidation of toluene into benzaldehyde and/orbenzoic acid under very mild conditions. The following resultswere obtained: （1） The selectivity of the oxidation depended onthe electronic density of double bonds. Reactivity was absentwhen strong electron-witherawing groups were conjugated with

引用

页码：833 / 838

页数：6

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