FluorescenceandpreparationofSr2(P2O7):Ce,Tbphosphatebyco-precipitationmethod

被引:8
作者
Cheng-Guo Ma
Wei Zheng
Li-Guo Jin
Li-Min Dong
机构
[1] SchoolofMaterialScience&Engineering,HarbinUniversityofScienceandTechnology
关键词
Phosphors; Co-precipitation method; Rare earth phosphate; Phosphorescence;
D O I
暂无
中图分类号
TN104.3 [显示材料];
学科分类号
0805 ; 080502 ;
摘要
The micron-sized Sr 2(P2O7):Ce,Tb green phosphors were prepared by being annealed at different temperatures with its precursors synthesized by co-precipitates of(NH4) 2HPO4 at ambient temperature. The phase structure, grain size, surface morphology, and luminescent properties of phosphors were investigated by X-ray diffraction, scanning electron microscope, transmission electron microscope, and fluorescence spectrum. The results show that the product of precursor annealed at 1,100 °C is Sr 2(P 2O7):Ce,Tb, which belongs to orthorhombic phase. The powder is spherical and the size distribution is in micron grade. The sample with the molar ratio of Sr/Tb/Ce of 100.0:0.4:0.6 shows the best fluorescence effect annealed at 1,100 °C for 3 h. The phosphors produce green fluorescence by being excitated with ultraviolet radiation of 254 nm wavelength, and the main emission peak is at 547 nm. The Sr 2(P2O7):Ce,Tb phosphors synthesized by co-precipitation method of precursors at ambient temperature is a kind of efficient green-emitting phosphors.
引用
收藏
页码:420 / 424
页数:5
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