A review on liquid metals as cathodes for molten salt/oxide electrolysis

被引：1
|
作者：
Shu-qiang Jiao [1 ,2 ]
Han-dong Jiao [2 ]
Wei-li Song [2 ]
Ming-yong Wang [1 ]
Ji-guo Tu [1 ]
机构：
[1] State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing
[2] Institute of Advanced Structure Technology, Beijing Institute of Technology
来源：
InternationalJournalofMineralsMetallurgyandMaterials | 2020年 / 27卷 / 12期
基金：
中国国家自然科学基金; 中央高校基本科研业务费专项资金资助;
关键词：
D O I：
暂无
中图分类号：
TF111.522 [];
学科分类号：
080601 ;
摘要：
Compared with solid metals, liquid metals are considered more promising cathodes for molten slat/oxide electrolysis due to their fascinating advantages, which include strong depolarization effect, strong alloying effect, excellent selective separation, and low operating temperature. In this review, we briefly introduce the properties of the liquid metal cathodes and their selection rules, and then summarize development in liquid metal cathodes for molten salt electrolysis, specifically the extraction of Ti and separation of actinides and rare-earth metals in halide melts. We also review recent attractive progress in the preparation of liquid Ti alloys via molten oxide electrolysis by using liquid metal cathodes. Problems related to high-quality alloy production and large-scale applications are cited, and several research directions to further improve the quality of alloys are also discussed to realize the industrial applications of liquid metal cathodes.
引用
收藏
页码：1588 / 1598
页数：11
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