ARamanStudyofSpinelLiMn2O4

被引:0
作者
WANG Chunzhong GONG Jie LIU Wei WEI Yingjin WU Feng and CHEN Gang Key Laboratory of Automobile Materials of Ministry of Education Alan G MacDirmid Institute and College of Materials Science and Engineering Jilin University Changchun P R China Institute of Condensed Matter Physics Jilin Normal University Siping P R China Beijing Institute of Technology Beijing P R China [1 ,2 ,1 ,1 ,3 ,1 ,1 ,130023 ,2 ,136000 ,3 ,100081 ]
机构
关键词
Raman characterization; Spinel; LiMn; 2O; 4;
D O I
暂无
中图分类号
O614 [金属元素及其化合物];
学科分类号
070301 ; 081704 ;
摘要
A Raman study was carried out for LiMn 2O 4, which was synthesized via the mixture of Mn 3O 4 and LiNO 3 sintered at different temperatures. It is shown that there are two kinds of Raman spectra for LiMn 2O 4 at different sintering temperatures, while the X-ray diffraction patterns of LiMn 2O 4 sintered at different temperatures are the same. Five Raman bands observed for the materials sintered below 500 ℃ are consistent with the theoretical prediction for spinel structure based on the group theory. Only two Raman bands were observed for the materials sintered at temperatures higher than 500 ℃. The best preparation condition for obtaining a good spinel LiMn 2O 4 is suggested based on the Raman study.
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页码:344 / 346
页数:3
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