Synthesis, Crystal Structure and Characterization of a New Zinc Citrate Complex

被引：0
|
作者：
林维臣 [1 ]
郭维刚 [1 ]
王丽华 [1 ]
马秀玲 [1 ]
项生昌 [1 ,2 ]
张章静 [1 ,3 ]
机构：
[1] College of Chemistry and Chemical Engineering, Fujian Provincial Key Laboratory of Polymer Materials, Fujian Normal University
[2] College of Life and Environmental Sciences, Minzu University of China
[3] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
来源：
Chinese Journal of Structural Chemistry | 2014年 / 04期
基金：
中国国家自然科学基金;
关键词：
zinc citrate; synthesis; crystal structure; photoluminescence;
D O I：
10.14102/j.cnki.0254-5861.2014.04.011
中图分类号：
O627.23 [锌族金属有机化合物];
学科分类号：
070303 ; 081704 ;
摘要：
A new Zn-citrate coordination complex {K[Zn(C6H5O7)(H2O)]}n(1) was synthesized via hydrothermal reaction. In the crystal structure of complex 1, each citrate serves as the quadricdentate ligand coordinating to three Zn(II) ions, forming a zigzag chain, and such chains are further connected into a 3D network by the K+ linkers. Crystal data for complex 1: triclinic, space group P1, a = 7.3487(9), b = 7.5397(6), c = 9.6772(8) ?, α = 76.894(8), β = 68.260(10), γ = 65.155(10)°, V = 450.34(7) ?3 and Z = 2. Other characterizations by elemental analysis, IR, TG and fluorescence were also described.
引用
收藏
页码：591 / 596
页数：6
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