Synthesis and Crystal Structure of H2Mo8O26〔（n-Bu）4N2〔（CH3）2 COHCH2COCH3〕2

被引：0
|
作者：
LU Xiao Ming (Department of Chemistry
机构：
来源：
结构化学 | 2000年 / 03期
关键词：
acetone; 4-methyl-4-hydroxy-2-pentone; octamolybdate; catalysis;
D O I：
10.14102/j.cnki.0254-5861.2000.03.002
中图分类号：
O76 [晶体结构];
学科分类号：
摘要：
The title compound 4 methyl 4 hydroxy 2 pentone is obtained by the condensed reaction of acetone, and co crystallized with octamolybdate anion and tetra butyl ammonium cation. The crystal structure belongs to triclinic system, space group P1 , Mo 8C 44 H 98 O 30 N 2 M r=1902.77, a=11.512(6), b=12.790(3), c=13.395(4), α=65.22(2), β=78.26(4), γ=71.12(3), V=1689(1) 3, Z=1, D x =1\^869g/cm 3, F(000)=950, μ =14.79 cm -1 , final R =0.053 and R w =0.067. The orbital hybridization of C(53) and C(55) are sp 3 and sp 2 separately in (CH 3) 2COHCH 2COCH 3 and the catalysis of β octamolybdate anion might be present for the condensed reaction of acetone.
引用
收藏
页码：163 / 167
页数：5
相关论文
共 50 条
  • [31] CRYSTAL AND MOLECULAR STRUCTURE OF [AL(CH3)3]2.C4H8O2
    ATWOOD, JL
    STUCKY, GD
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (21) : 5362 - &
  • [32] Structures of Pt2(CH3)4(S(CH3)2)2 and [PtPh2(S(CH3)2)]n (n=2, 3)
    Song, DT
    Wang, SN
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 648 (1-2) : 302 - 305
  • [33] REPRESENTATION AND CRYSTAL-STRUCTURE OF [N(CH3)4]ZN2(N3)5.H2O
    MAUTNER, FA
    KRISCHNER, H
    KRATKY, C
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1985, 172 (3-4): : 291 - 296
  • [34] Preparation, crystal structure and theoretical calculation of (CH3)2NH2+ C2N4O3H-
    Ma, HX
    Song, JR
    Xu, KZ
    Hu, RZ
    Zhai, GH
    Wen, ZY
    Yu, KB
    ACTA CHIMICA SINICA, 2003, 61 (11) : 1819 - 1823
  • [35] Synthesis and characterization of {[(n-BU)2Sn(O2CCH=CHAr)]2O}2 and crystal structure of {[(n-BU)2Sn(O2CCH=CHPh)]2O}2
    Yin, HD
    Wang, CH
    Ma, CL
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2004, 43 (12): : 2623 - 2627
  • [36] PREPARATION AND CRYSTAL-STRUCTURE OF SR(N3)2 . OS(CH3)2 . H2O
    TAEB, A
    KRISCHNER, H
    KRATKY, C
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1986, 176 (1-2): : 97 - 102
  • [37] Synthesis and properties of [NR4]3[SbS4] (R = Me, Et, n- Pr, n- Bu) and the crystal structures of [N(n-Bu)4 ] 3 [SbS4 ] •6H2O and [N(n-Bu)4 ] 3 [Sb(S2O3)3 ] middot2THF
    King, Rhys P.
    Levason, William
    Reid, Gillian
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1278
  • [38] THE CRYSTAL-STRUCTURE OF [(CH3)2N(CH2)2(CH2)2O]2NAAG3I6.2H2O
    GELLER, S
    XIE, SS
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1986, 177 (1-2): : 59 - 65
  • [39] STUDIES ON SYNTHESIS, STRUCTURE AND PROPERTIES OF THE CLUSTER COMPOUND, [BU4N]3[MO2FES8O] . (CH2OH2)
    ZHANG, ZG
    SUN, WT
    NIU, SY
    LI, SQ
    YANG, GD
    ACTA CHIMICA SINICA, 1989, 47 (11) : 1061 - 1064
  • [40] Synthesis and crystal structure of the complexes [(n-Bu)4N]2[{(THF)Cl4ReN}2PdCl2], [Ph4P]2[(THF)Cl4ReN-PdCl(μ-Cl)2 and [(n-Bu)4N]2[Pd3Cl8]
    Schwarz, S
    Strähle, J
    Weisser, U
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (11): : 2495 - 2499
12345