Synthesis and Crystal Structure of H2Mo8O26〔（n-Bu）4N2〔（CH3）2 COHCH2COCH3〕2

被引：0
|
作者：
LU Xiao Ming (Department of Chemistry
机构：
来源：
结构化学 | 2000年 / 03期
关键词：
acetone; 4-methyl-4-hydroxy-2-pentone; octamolybdate; catalysis;
D O I：
10.14102/j.cnki.0254-5861.2000.03.002
中图分类号：
O76 [晶体结构];
学科分类号：
摘要：
The title compound 4 methyl 4 hydroxy 2 pentone is obtained by the condensed reaction of acetone, and co crystallized with octamolybdate anion and tetra butyl ammonium cation. The crystal structure belongs to triclinic system, space group P1 , Mo 8C 44 H 98 O 30 N 2 M r=1902.77, a=11.512(6), b=12.790(3), c=13.395(4), α=65.22(2), β=78.26(4), γ=71.12(3), V=1689(1) 3, Z=1, D x =1\^869g/cm 3, F(000)=950, μ =14.79 cm -1 , final R =0.053 and R w =0.067. The orbital hybridization of C(53) and C(55) are sp 3 and sp 2 separately in (CH 3) 2COHCH 2COCH 3 and the catalysis of β octamolybdate anion might be present for the condensed reaction of acetone.
引用
收藏
页码：163 / 167
页数：5
相关论文
共 50 条
  • [1] Synthesis and crystal structure of H2Mo8O26[(n-Bu)4N]2[(CH3)2COHCH2COCH3]2
    Lu, XM
    Li, WJ
    Mao, XA
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (03) : 163 - 167
  • [2] H2Mo8O26[（n-Bu）4N]2[（CH3）2COHCH2COCH3]2的合成与晶体结构
    张钟宪
    鲁晓明
    刘顺诚
    化学通报, 2000, (03) : 41 - 42
  • [3] SYNTHESIS AND CHARACTERIZATION OF THE COMPLEXES OF MO(V) AND MO(VI) WITH THE LIGANDS "HSCH2CH2N(CH3)(CH2)NN(CH3)CH2CH2SH, N= 2,3 - CRYSTAL-STRUCTURE OF H2[MO2O4(SCH2CH2N(CH3)(CH2)3N(CH3)CH2CH2S)2]
    KIM, N
    KIM, S
    VELLA, PA
    ZUBIETA, J
    INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1978, 14 (12): : 457 - 464
  • [4] Synthesis　and　Crystal　Structure　of［（n－Bu）4N］2［Mo4O10(OC10H6O)2（OCH3）2］
    Lu Xiao-Ming
    Zhu Hui-Ju
    Yang Ning
    Liu Shun-Cheng
    Jin Xiang-Lin(Department of Chemistry
    结构化学, 1995, (02) : 135 - 138
  • [5] SOLVENT-FREE SYNTHESIS OF TETRAMETHYLAMMONIUM SALTS - SYNTHESIS AND CHARACTERIZATION OF [N(CH3)(4)](2)[C2O4], [N(CH3)(4)][CO3CH4], [N(CH3)(4)][NO2], [N(CH3)(4)][CO2H], AND [N(CH3)(4)][O2C(CH2)(2)CO2CH3]
    ALBERT, B
    JANSEN, M
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (10): : 1735 - 1740
  • [6] The synthesis,1H NMR and IR study of [(n-Bu)4N]2 MO2O5(OC10H6O)2] and [(n-Bu)4N]2 [Mo4O10H6O)2 (OCH3)2]
    Lu, XM
    Zhu, HJ
    Yuan, HZ
    Mao, XA
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2002, 22 (01) : 36 - 38
  • [7] Synthesis and structure of (NH4)4[(DMF)2Mo8O26]•2CH3CH2OH•2H2O (DMF=N,N-dimethylformamide)
    Zhang, Quan-Zheng
    Shao, Guo-Quan
    Chen, Gang
    Shen, Huan
    Lu, Guo-Hui
    Ping, Rang
    Xie, Peng-Fei
    Jiang, Yang
    Zhang, Jie
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2007, 37 (05) : 369 - 373
  • [8] Synthesis and structure of (NH4)4[(DMF)2Mo8O26]· 2CH3CH2OH·2H2O (DMF=N, N-dimethylformamide)
    Quan-Zheng Zhang
    Guo-Quan Shao
    Gang Chen
    Huan Shen
    Guo-Hui Lu
    Rang Ping
    Peng-Fei Xie
    Yang Jiang
    Jie Zhang
    Journal of Chemical Crystallography, 2007, 37 : 369 - 373
  • [9] SYNTHESIS AND CRYSTAL-STRUCTURE OF MG[SI(CH3)3]2.(CH3)2NCH2CH2CH2N(CH3)2
    ROSCH, L
    PICKARDT, J
    IMME, S
    BORNER, U
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1986, 41 (12): : 1523 - 1526
  • [10] The Synthesis, 1H NMR and IR Study of [(n-Bu)4N]2[Mo2O5(OC 10H6O)2] and [(n-Bu)4N]2[Mo4O10(OC 10H6O)2(OCH3)2 ]
    Lu, Xiao-Ming
    Zhu, Hui-Ju
    Yuan, Han-Zhen
    Mao, Xi-An
    Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis, 2002, 22 (01):
12345