THEORETICAL ANALYSIS OF KINETICS OF NONISOTHERMAL CRYSTALLIZATION OF POLYMERS

被引:3
|
作者
张志英
机构
[1] Department of Textile Chemical Engineering
[2] Tianjin 300160
[3] Tianjin Institute of Textile Science and Technology
关键词
Crystallization kinetics; Nonisothermal crystallization; Avrami theory; Poly (ethylene terephthalate);
D O I
暂无
中图分类号
O631.3 [高聚物的化学性质];
学科分类号
摘要
The classical crystallization theories proposed by Avrami, Evans, and Mandelkern wereextended to the nonisothermal situation. The expressions derived from the classical equations canbe expressed in either the differential form or the integral form. A method was provided so as toobtain the parameters characterizing the crystallization rate and mechanism from DSC curves withseveral constant heating or cooling rates. The rate constants of crystallization obtained from bothisothermal and nonisothermal curves of poly(ethylene terephthalate)were compared.
引用
收藏
页码:256 / 265
页数:10
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